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Its a chemical reaction that turns calcium carbonate into calcium acetate due to the acetic properties in vinegar. It doesen have to be vite, but there is probablu some more cleanup jub if you use a red one or balsamic...
I still think everyone should try the citric acid (you buy iy as a crystalized powder).
Using all sorts of pads, rubbing it off, may seem like a effective way, but I asure you that you are putting microscopig scratches in the glass that will eventually show AND will cause the calcium carbonate to attach better/faster in the future.
Do you mix the citric acid crystals with water? How do you apply it to the glass? Do you spray it on?
I just cut a lemon in half and use it to wipe the glass squeezing it as I go. Let it sit for 5 to 10 minutes and then rinse it off with water. I have removed stains that have been on one of my tanks for 17 years this way, it is pretty amazing.